Derivation EtOH and H20 Formula:
This Derivation is an mathematical addition to my
article about Alcohol Dilution
and it expains the arithmetic behind my
online delution/fortification calucators
First, denote:
- \(\rho_{100}\) - density of pure EtOH
- \(\rho_{x}\) - density of Mixture
- \( V_{100}\) - volume of pure EtOH
- \( V_{x}\) - volume of Mixture
- \( \mu \) - EtOH weight ratio to total weight of Mixture, ABW
- \( \sigma \) - EtOH volume ratio to total volume of Mixture, ABV
We are mixing pure EtOH with water and the initial mass of EtOH is:
$$ M_{EtOH} = \rho_{100} * V_{100} \tag{1} $$
The mass of EtOH portion in Solution would be
$$ M_{EtOH} = \mu * \rho_x * V_x \tag{2} $$
Equating (1) nad (2)
$$ \rho_{100} V_{100} = \mu \rho_x V_x \tag{3} $$
or
$$ \frac{V_{100}}{V_x}= \mu \frac{\rho_x} {\rho_{100}} \tag{4} $$
From ABV definition:
$$ \sigma = \frac{V_{100}}{V_x} \tag{5} $$
From (4) nad (5)
$$ \sigma = \mu \frac{\rho_x}{\rho_{100}} \tag{5} $$
Equivalently,
$$ \mu = \sigma \frac{\rho_{100}}{\rho_{x}} \tag{6} $$
Now, Let’s mix two solutions \( (V_1, \sigma_1) + (V_2, \sigma_2) -> (V_3, \sigma_3)\)
By definition of ABW,
$$ \mu_3 = \frac{M_1^{EtOH} + M_2^{EtOH}} {M_{tot}} $$
or,
$$ \mu_3 = \frac{V_1\rho_1\mu_1 + V_2\rho_2\mu_2}{V_1\rho_1 + V_2\rho_2} \tag{7} $$
Substitute (6) into (7),
$$ \frac{\sigma_3 \rho_{100}}{\rho_3} =
\frac{ (V_1 \rho_1 \sigma_1 \rho_{100}) / \rho_1
+ ( V_2 \rho_2 \sigma_2 \rho_{100}) / \rho_2 }
{(V_1 \rho_1 + V_2 \rho_2)} \tag{8} $$
Reducing both parts on common variables gives:
$$ \frac{\sigma_3}{\rho_3} = \frac{V_1 \sigma_1 + V_2 \sigma_2}{V_1 \rho_1 + V_2 \rho_2} \tag{9} $$
In practical case, we know initial Volume and ABVs for two reagents and product: \( V_1, \sigma_1, \sigma_2, \sigma_3,\). Usually, We need to find \(V_2\)
Let's resolve (9) in repect to \(V_2\):
$$ V_2 = \frac{\sigma_1 \rho_3 - \sigma_3 \rho_1}
{\sigma_3 \rho_2 - \sigma_2 \rho_3} V_1 \tag{10} $$
Generals equation (10) can be reduced for case of mixing EtOH with pure water. In this case
\(\sigma_2=0\) and \( \rho_2 \approx 1 \):
$$ V_2 = ( \frac{\sigma_1}{\sigma_3} \rho_3 - \rho_1) V_1 \tag{11} $$
The formulas (10) and (11) are working formula for our
Alcohol calculators
where \(\rho\) (density) is an empirical values interpolated
from tables
\(\rho = \rho(\mu(\sigma)) \)